#rosenthal's_reagent
Rosenthal's reagent
Rosenthal's reagent is a metallocene bis(trimethylsilyl)acetylene complex with zirconium (Cp2Zr) or titanium (Cp2Ti) used as central atom of the metallocene fragment Cp2M. Additional ligands such as pyridine or THF are commonly used as well. With zirconium as central atom and pyridine as ligand (Zirconocene bis(trimethylsilyl)acetylene pyridine), a dark purple to black solid with a melting point of 125–126 °C is obtained. Synthesizing Rosenthal's reagent of a titanocene source yields golden-yellow crystals of the titanocene bis(trimethylsilyl)acetylene complex with a melting point of 81–82 °C. This reagent enables the generation of the themselves unstable titanocene and zirconocene under mild conditions.
Wed 18th
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