Bismuth subhalides

Bismuth-containing solid-state compounds pose an interest to both the physical inorganic chemists as well as condensed matter physicists due to the element's massive spin-orbit coupling, stabilization of lower oxidation states, and the inert pair effect. Additionally, the stabilization of the Bi in the +1 oxidation state gives rise to a plethora of subhalide compounds with interesting electronics and 3D structures.

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