Keywords

#carroll_rearrangement

Carroll rearrangement

Chemical reaction

The Carroll rearrangement is a rearrangement reaction in organic chemistry and involves the transformation of a β-keto allyl ester into a α-allyl-β-ketocarboxylic acid. This organic reaction is accompanied by decarboxylation and the final product is a γ,δ-allylketone. The Carroll rearrangement is an adaptation of the Claisen rearrangement and effectively a decarboxylative allylation.

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Carroll rearrangement Sigmatropic reaction Claisen rearrangement Allyl group Tris(dibenzylideneacetone)dipalladium(0) Organopalladium chemistry Geranylacetone Jirō Tsuji List of organic reactions The Founder
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