Keywords

#kulinkovich_reaction

Kulinkovich reaction

Chemical reaction

The Kulinkovich reaction describes the organic synthesis of substituted cyclopropanols through reaction of esters with dialkyl­dialkoxy­titanium reagents, which are generated in situ from Grignard reagents containing a hydrogen in beta-position and titanium(IV) alkoxides such as titanium isopropoxide. This reaction was first reported by Oleg Kulinkovich and coworkers in 1989.

Sat 20th

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Kulinkovich reaction Tebbe's reagent List of inorganic reactions Titanium isopropoxide List of organic reactions Cyclopropanation Organotitanium chemistry Lombardo methylenation
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