Keywords

#non-nucleophilic_base

Non-nucleophilic base

As the name suggests, a non-nucleophilic base is a sterically hindered organic base that is a poor nucleophile. Normal bases are also nucleophiles, but often chemists seek the proton-removing ability of a base without any other functions. Typical non-nucleophilic bases are bulky, such that protons can attach to the basic center but alkylation and complexation is inhibited.

Fri 22nd

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Non-nucleophilic base N,N-Diisopropylethylamine Potassium bis(trimethylsilyl)amide 1,8-Diazabicyclo(5.4.0)undec-7-ene Lithium bis(trimethylsilyl)amide 2-Methoxyethoxymethyl chloride Sodium tert-butoxide 2,2,6,6-Tetramethylpiperidine SN2 reaction Lithium tetramethylpiperidide
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