Phosphoramidite ligand

A phosphoramidite ligand is any phosphorus-based ligand with the general formula P(OR1)(OR2)(NRR'). Chiral versions of these ligands, particularly those derived from the BINOL scaffold, are widely used in enantioselective synthesis. The application of phosphoramidites as effective monodentate ligands for transition metal catalysis was first reported by Dutch chemist Ben Feringa. The introduction of phosphoramidite ligands challenged the notion that high flexibility in the metal–ligand complex is detrimental for high stereocontrol.

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