Saturated absorption spectroscopy

Saturated absorption spectroscopy measures the transition frequency of an atom or molecule between its ground state and an excited state. In saturated absorption spectroscopy, two counter-propagating, overlapped laser beams are sent through a sample of atomic gas. One of the beams stimulates photon emission in excited atoms or molecules when the laser's frequency matches the transition frequency. By changing the laser frequency until these extra photons appear, one can find the exact transition frequency. This method enables precise measurements at room temperature because it is insensitive to doppler broadening. Absorption spectroscopy measures the doppler-broadened transition, so the atoms must be cooled to millikelvin temperatures to achieve the same sensitivity as saturated absorption spectroscopy.

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