#metal-catalyzed_σ-bond_rearrangement

Metal-catalyzed σ-bond rearrangement

The metal ion-catalyzed σ-bond rearrangement is a collection of chemical reactions that occur with highly strained organic compounds are treated with metal ions like Ag+, Rh(I), or Pd(II) based reagents. [2+2] ring openings are sometimes observed:

Sat 20th

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