Keywords

#sigma-bond_metathesis

Sigma-bond metathesis

In organometallic chemistry, sigma-bond metathesis is a chemical reaction wherein a metal-ligand sigma bond undergoes metathesis (exchange of parts) with the sigma bond in some reagent. The reaction is illustrated by the exchange of lutetium(III) methyl complex with a hydrocarbon (R-H):(C5Me5)2Lu-CH3 + R-H → (C5Me5)2Lu-R + CH4

Sat 20th

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Sigma-bond metathesis Organometallic chemistry Carbon–hydrogen bond activation Methane functionalization Alkyne Transition metal silyl complexes Alkene Lanthanocene Metal-catalyzed σ-bond rearrangement Ring-closing metathesis
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